CAS 37342-97-5 | Bis(cyclopentadienyl)zirconium Chloride Hydride

Name:Bis(cyclopentadienyl)zirconium chloride hydride

Synonyms:Bis(cyclopentadienyl)zirconium Chloride Hydride;zirconocene hydride;SCHWARTZ REAGENT;ZIRCONOCENE HYDROCHLORIDE;SCHWART'S REAGENT;dicyclopentadienylzirconium hydrochloride;Zirconocene Chloride Hydride;Schwartz's;SCHWARTZ'S REAGENT;Zirconocene(IV) chloride hydride;

CAS:37342-97-5

Purity:>96.0%

Molecular Formula:C₁₀H₁₁ClZr

Molecular Weight:257.87

Melting Point:300ºC

Boiling Point:41.5ºC at 760 mmHg

Density:N/A

PSA:0.00

LogP:-0.24

Appearance:white to beige powder

Stability:light sensitive, moisture sensitive

Water solubility:reacts

Storage condition:Keep in dark place,Inert atmosphere,2-8°C

InchI:InChI=1S/2C5H5.ClH.Zr.H/c2*1-2-4-5-3-1;;;/h2*1-5H;1H;;/q;;;+1;/p-1

InchI Key:PSYHEBZUPSHSKK-UHFFFAOYSA-M

Application:Bis(cyclopentadienyl)zirconium hydridochloride is used in the conversion of amides to aldehydes. It is also used as a pharmaceutical intermediate.

Reference:

Jared T Spletstoser.; Jonathan M White.; Ashok Rao Tunoori.; Gunda I Georg. Mild and selective hydrozirconation of amides to aldehydes using Cp2Zr(H)Cl: scope and mechanistic insight.. Journal of the American Chemical Society. 2007, 129 (11), 3408-3419.

Thomas E. Cole.; Ramona. Quintanilla.; Stephan. Rodewald. Migration of 1-alkenyl groups from zirconium to boron compounds. Organometallics. 1991, 10 (10), 3777-3781.

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