CAS 12116-66-4 Hafnocene Dichloride

CAS 12116-66-4 Hafnocene Dichloride

Name:Hafnocene Dichloride
CAS:12116-66-4
Purity:98%
Molecular Formula:C10H10Cl2Hf
Molecular Weight:379.59
Melting Point:230-233ºC
Boiling Point:N/A

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Product Introduction

Name:Hafnocene Dichloride

Synonyms:Bis(cyclopentadienyl)hafnium Dichloride;Hafnium, dichlorobis(h5-2,4-cyclopentadien-1-yl)-;

CAS:12116-66-4

Purity:98%

Molecular Formula:C10H10Cl2Hf

Molecular Weight:379.59

Melting Point:230-233ºC

Boiling Point:N/A

Density:12.7g/cm3

PSA:0.00

LogP:3.30

Appearance:Gray powder

Stability:moisture sensitive

Solubility:Soluble in aromatic solvents, chloroform; slightly soluble in THF, ether. Insolble in hexanes.

Storage condition:Store at room temperature

InchI:InChI=1S/2C5H5.2ClH.Hf/c2*1-2-4-5-3-1;;;/h2*1-5H;2*1H;/q;;;;+2/p-2

InchI Key:UHCOEQZUSAFLHQ-UHFFFAOYSA-L

Application:Starting material to prepare many kinds of hafnocene(II or IV) derivatives; in combination with AgI salt, is an effective activator for glycosyl fluoride. Pharmaceutical intermediates and alos used in chemical research.

Reference:

Charles H. Winter,; Xiao Xing. Zhou,; Daniel A. Dobbs,; Mary Jane. Hees.Cyclopentadienylmetal trichloride formation versus metallocene dichloride formation in the reactions of silylated cyclopentadienes with zirconium and hafnium chlorides. Crystal structure of (1,3-bis(trimethylsilyl)cyclopentadienyl)titanium trichloride. Organometallics, 1991 , 10 (1) ,210-214.

 

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