CAS 171730-81-7 | DFEC Li-ion Battery Electrolyte Additive | China Manufacturer
Product Name: Difluoroethylene Carbonate (DFEC)
Synonym: 4,5-Difluoro-1,3-dioxolan-2-one; trans-4,5-Difluoro-1,3-dioxolan-2-one
CAS Number: 171730-81-7
Molecular Formula: C3H2F2O3
Molecular Weight: 124.04 g/mol
Purity: ≥ 99% (battery grade)
Appearance: Colorless transparent liquid
Moisture: ≤ 20 ppm
Application: Li-ion / Li-metal battery electrolyte additive
Packaging: 100g / 1kg / 25kg / 200kg (custom available)
Lead Time: 3–7 business days from stock
Made in China | COA & SDS provided with every shipment
- Worldwide Delivery
- Quality Assurance
- 24/7 Customer Service
Product Introduction
CAS 171730-81-7 | Difluoroethylene Carbonate (DFEC) | Li-ion Battery Electrolyte Additive | China Manufacturer
Product Overview
As a China-based manufacturer, Alfa Chemical supplies Difluoroethylene Carbonate (DFEC, CAS 171730-81-7), a fluorinated cyclic carbonate used as an electrolyte additive in lithium-ion and lithium-metal batteries. DFEC features two fluorine atoms in its molecular structure, giving it a lower LUMO energy level than conventional carbonate solvents. This enables preferential reduction on the anode surface, forming a LiF-rich solid electrolyte interphase (SEI) that suppresses lithium dendrite growth and improves cycling stability.[reference:5]
The product is supplied as a colorless transparent liquid with purity ≥ 99% and moisture content ≤ 20 ppm, suitable for direct use in electrolyte formulation. Compared with fluoroethylene carbonate (FEC), DFEC shows advantages at low temperatures, with studies reporting a six-fold increase in desolvation rate at −20 °C. It also performs well at high voltage, with Li||NCM811 full cells retaining up to 75% capacity after 200 cycles at 4.5 V.[reference:6][reference:7]
DFEC is compatible with common electrolyte salts (LiPF₆, LiFSI) and co-solvents (EC, DEC, EMC). It can be used as a single additive or in combination with other film-forming additives. For related battery electrolyte additives and fluorinated materials, explore our Material Science range.

Industrial Applications
DFEC is used as an electrolyte additive in advanced battery systems where stable interfacial chemistry and wide-temperature performance are required. The four application areas below cover the main uses of CAS 171730-81-7.
Challenge: High-voltage operation (≥4.5 V) causes electrolyte decomposition and cathode degradation, limiting cycle life.
Solution: DFEC forms a thin, robust passivation layer on both anode and cathode, suppressing side reactions.
Result: Li||NCM811 full cells retain up to 75% capacity after 200 cycles at 4.5 V. DFEC-based electrolytes outperform FEC-based counterparts at high voltage.[reference:8]
Request technical data →Challenge: Conventional carbonate electrolytes suffer from poor ionic conductivity and sluggish desolvation at sub-zero temperatures.
Solution: DFEC as co-solvent or additive reduces Li⁺ desolvation energy barrier.
Result: Six-fold increase in desolvation rate at −20 °C compared with baseline electrolytes. DFEC outperforms FEC at low temperatures.[reference:9]
Request a quote →DFEC promotes the formation of a stable LiF-rich SEI on lithium metal anodes, inhibiting dendrite growth. A study using DFT simulations confirmed that DFEC undergoes a unique double-defluorination pathway generating additional LiF, potentially enhancing SEI stability.[reference:10]
Request a sample →DFEC improves electrolyte flash point and provides flame-retardant effects. DFEC-based electrolytes also demonstrate superior safety performance in typical safety tests.[reference:11]
Discuss custom needs →Technical Specifications
Specifications for DFEC (CAS 171730-81-7) are listed below. For batch-specific COA or SDS, please contact us.
| Item | Specification |
|---|---|
| Product Name | Difluoroethylene Carbonate (DFEC) |
| Synonym | 4,5-Difluoro-1,3-dioxolan-2-one; trans-4,5-Difluoro-1,3-dioxolan-2-one |
| CAS Number | 171730-81-7 |
| Molecular Formula | C3H2F2O3 |
| Molecular Weight | 124.04 g/mol |
| Appearance | Colorless transparent liquid |
| Purity (GC) | ≥ 99% (battery grade) |
| Moisture | ≤ 20 ppm (Karl Fischer) |
| Density | 1.52 ± 0.1 g/cm³ (predicted)[reference:12] |
| Boiling Point | ~90–93 °C[reference:13] |
| Storage Condition | 2–8 °C, protected from light, under inert atmosphere |
| Packaging Options | 100g / 1kg / 25kg / 200kg, custom available |
| Documents | COA with GC purity and moisture data; SDS available on request |
Test methods: purity by GC; moisture by Karl Fischer titration. Full analytical data available in batch-specific COA.
Quality Documentation
Batch-specific Certificate of Analysis with GC purity and moisture data.
Safety Data Sheet for safe handling, storage, and transport documentation.
Discuss formulation compatibility, additive ratios, or custom requirements.
Manufacturing & Quality Control
DFEC is produced on a dedicated fluorinated carbonate line with controlled synthesis and purification. Each batch is tested by GC for purity and by Karl Fischer titration for moisture before release. The product is handled and packaged under inert atmosphere to maintain low moisture content.
The facility is ISO 9001 certified, and each batch is assigned a traceable lot number. A Certificate of Analysis (COA) and Safety Data Sheet (SDS) ship with every order. Learn more about our facilities →
Packaging & Shipping
Stock items ship in 3–7 business days. Samples go by international express; bulk orders by air or sea freight. COA and SDS ship with every order.
100g / 1kg / 25kg / 200kg. Amber glass or HDPE containers with inert gas blanket. Custom quantities available.
International express for samples; air or sea freight for bulk orders. Stock items ship in 3–7 business days.
COA with GC purity and moisture data; SDS; commercial invoice; packing list. HS code provided on request.
Store at 2–8 °C, protected from light, under inert atmosphere. Keep containers tightly closed.
For special packaging or urgent requests, please contact our team directly.
Why Choose Alfa Chemical
Battery electrolyte additives require consistent purity, ultra-low moisture, and reliable supply. Here is what Alfa Chemical provides for DFEC.
Purity ≥ 99%, moisture ≤ 20 ppm. Each batch is tested by GC and Karl Fischer titration before release.
Packaged under inert gas to maintain low moisture and prevent degradation during storage and transport.
Technical support for additive ratios, co-solvent selection, and electrolyte formulation optimization.
100g R&D samples, 1kg pilot quantities, and 25kg bulk orders. Stock items ship in 3–7 business days.
Frequently Asked Questions
DFEC is used as an electrolyte additive in lithium-ion and lithium-metal batteries. It forms a LiF-rich SEI layer that improves cycling stability and suppresses dendrite growth.
DFEC has two fluorine atoms (vs one in FEC). DFEC performs better at low temperatures and can outperform FEC at high voltage. Both form LiF-rich SEI layers, but DFEC has a unique double-defluorination pathway generating additional LiF.[reference:14]
Purity is ≥ 99% by GC. Moisture is ≤ 20 ppm by Karl Fischer titration. Batch-specific COA is available.
Yes, COA with GC purity and moisture data, and SDS are provided with every shipment.
Store at 2–8 °C, protected from light, under inert atmosphere. Keep containers tightly closed.
The smallest standard pack is 100g. Custom quantities are available. Contact us for your specific requirement.
DFEC is typically used at 1–5 wt% in the electrolyte. The optimal ratio depends on your specific battery chemistry and operating conditions. Please contact us for formulation guidance.
Yes. We can discuss custom synthesis of related fluorinated carbonates and bulk supply. Please share your target specification when inquiring.
Need a quote or sample for CAS 171730-81-7? We reply within 12 hours. COA and SDS ship with every order.
Get a Quote Request SampleRelated products & resources:
Alfa Chemical Co., Ltd is a China-based manufacturer of specialty chemicals and battery materials, based in Zhengzhou, China. We supply Difluoroethylene Carbonate (CAS 171730-81-7) and related fluorinated electrolyte additives to battery manufacturers worldwide.
* All product specifications are for reference purposes. Users should conduct their own suitability tests under actual conditions. This product is for R&D and industrial use only. Not for pharmaceutical, food, or cosmetic applications without specific regulatory compliance testing.
Last updated: September 24, 2026.
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