CAS:15629-92-2 | [1,3-Bis(diphenylphosphino)propane]nickel(II) Chloride

Name:[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride

Synonyms:1,3-BIS(DIPHENYLPHOSPHINE)PROPANE NICKEL(II) CHLORIDE;[1,3-BIS(DIPHENYLPHOSPHINO)PROPANE]DICHLORONICKEL(II);1,3-BIS(DIPHENYLPHOSPHINO)PROPANE NICKEL (II) CHLORIDE;[1,3-BIS(DIPHENYLPHOSPHINO)PROPANE]NICKEL(II) DICHLORIDE;

CAS:15629-92-2

Purity:99%

MDL No:MFCD00015318

Molecular Formula:C₂₇H₂₆P₂•NiCl₂

Molecular Weight:542.04

Melting Point:213 °C (dec.)(lit.) 

Boiling Point:N/A

Appearance:Red to red-brown powder

Sensitivity:Moisture sensitive

Water solubility:insoluble

Hydrolytic Sensitivity:4: no reaction with water under neutral conditions

Storage condition:Inert atmosphere,Room Temperature

InchI:InChI=1S/C27H26P2.2ClH.Ni/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27;;;/h1-12,14-21H,13,22-23H2;2*1H;/q;;;+2/p-2

InChIKey:ZBQUMMFUJLOTQC-UHFFFAOYSA-L

Packaging & Delivery

Package:5g/10g/25g/50g/bulk package

Transportation: by FeDex or by ocean shipping or clients requirement

Delivery Detail: Within 3-5 days after full payment

Flexible payment terms: support T/T, Paypal , Credit Card

Application:[1,3-Bis(diphenylphosphino)propane]nickel(II) Chloride is used as an effective catalyst for Kumada coupling and Suzuki reactions. It also catalyzes other reactions to convert enol ethers, dithioacetals and vinyl sulfides to olefins.

 References:

Li, J., et al.: J. Polym. Res., 19, 1-9 (2012); Yamamoto, T., et al.: Tetrahedron Lett., 42, 8653-8656 (2001);

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