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CAS:14647-23-5 | [1,2-Bis(diphenylphosphino)ethane]dichloronickel(II)
Molecular Formula: C26H24Cl2NiP2
Molecular Weight:528.02
Purity:98%
Package:5g/10g/25g/50g/bulk package
Transportation: FeDex/DHL/ocean shipping /clients requirement
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Product Introduction
Name | [1,2-Bis(diphenylphosphino)ethane]dichloronickel(II) |
Synonyms | 1,2-Bis-(Diphenylphosphino)EthaneDichloroNickel;1,2-Bis-(Diphenylphosphino)Eth |
CAS | 14647-23-5 |
MDL No | MFCD00013313 |
Boiling Point | 514.8ºC at 760mmHg |
Melting Point | 263-265 °C(lit.) |
Flash Point | 281.7ºC |
PSA | 27.18 |
Appearance | Yellow to brown powder,crystals and/or chunks |
Sensitivity | Moisture sensitive |
Solubility | Chloroform, Methanol (Sparingly) |
Vapour Pressure | 3.38E-10mmHg at 25°C |
Storage condition | Store in cool place. Keep container tightly closed in a dry and well-ventilated place |
Application:Dichloro[bis(1,2-diphenylphosphino)ethane]nickel(II)(CAS:14647-23-5) is a reactant involved in Kumada catalyst-transfer polycondensation, oxidation of carboranyl phosphine ligands, synthesis of nickel-iron dithiolato hydrides, Ullmann reactions - homocoupling reactions, co-catalyst for hydroformylation of alcohols for the synthesis of quaternary carbon centers, catalyst for Wacker-type intramolecular aerobic oxidative amination of alkenes.
References:
Bryan E Barton; C Matthew Whaley; Thomas B Rauchfuss; Danielle L Gray. Nickel-iron dithiolato hydrides relevant to the [NiFe]-hydrogenase active site. Journal of the American Chemical Society. 2009, 131 (20), 6942-6943.
Yusuke Ueki; Hideto Ito; Ippei Usui; Bernhard Breit. Formation of quaternary carbon centers by highly regioselective hydroformylation with catalytic amounts of a reversibly bound directing group. Chemistry: A European Journal. 2011, 17 (31), 8555-8558.
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