CAS 145926-28-9 | (R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthaleneChloro(P-cymene)ruthenium Chloride
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CAS 145926-28-9 | (R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthaleneChloro(P-cymene)ruthenium Chloride

CAS 145926-28-9 | (R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthaleneChloro(P-cymene)ruthenium Chloride

Name:(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthaleneChloro(P-cymene)ruthenium chloride
CAS:145926-28-9
Purity:98%
Molecular Formula:C54H46Cl2P2Ru
Molecular Weight:928.88
  Melting Point:N/A
Boiling Point:724.3°C at 760 mmHg

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Product Introduction

Name:(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthaleneChloro(P-cymene)ruthenium chloride

Synonyms:Chloro[(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-Binaphthyl](P-cymene)ruthenium (II) chloride
Chloro[(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-Binaphthyl](P-cymene)ruthenium (II) chloride
(R)-(+)-2,2'-[Bis(diphenylphosphino)-1,1'-Binaphthyl]Chloro(P-cymene)ruthenium
[(R)-2,2'-Bis-(diphenylphosphino)-1,1'-Binaphthyl]-Chloro-(P-cymene)-rutheniumchloride
[(S)-2,2'-Bis-(diphenylphosphino)-1,1'-Binaphthyl]-Chloro-(P-cymene)-rutheniumchloride
(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthaleneChloro(P-cymene)ruthenium chloride

CAS:145926-28-9

Purity:98%

Molecular Formula:C54H46Cl2P2Ru

Molecular Weight:928.88

Melting Point:N/A

Boiling Point:724.3°C at 760 mmHg

Flash Point:419°C

Density:N/A

Vapor Presure:5.55E-20mmHg at 25°C

Appearance:Light yellow to Brown powder to crystal

Stability:Air Sensitive

Water solubility:Insoluble

Storage condition:Store at 4° C

InChI:InChI=1/C44H32P2.C10H14.2ClH.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;1-8(2)10-6-4-9(3)5-7-10;;;/h1-32H;4-8H,1-3H3;2*1H;/q;;;;+2/p-2

Application:(R)-RuCl[(p-cymene)(BINAP)]Cl is a ruthenium BINAP catalysts.

Reference:

V. H. Rane, D. Tas, R. F. Parton, P. A. Jacobs, Catal. Lett. 1996, 41, 111. 

U. Schmidt, V. Leitenberger, H. Griesser, J. Schmidt, R. Meyer, Synthesis 1992, 12, 1248.

Yue, C., et al.: Yingyong Huagong, 43, 1042 (2014); Bernas, H., et al.: Catal. Sci. Technol., 2, 1901 (2012)


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