CAS:64536-78-3 | (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) Hexafluorophosphate
Molecular Formula:C31H50F6IrNP2
Molecular Weight:804.89 g/mol
Purity:98%
Package:5g/10g/25g/50g/bulk package
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Product Introduction
Applications
1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate(CAS:64536-78-3) is used as a catalyst for hydrogenation of mono-, di-, tri-, and tetra-substituted substrates and the isomerization and hydroboration of alkenes. It is also used in isotope exchange reactions, especially the direct exchange of a hydrogen atom with its isotopes deuterium and tritium. Carbonyl groups are also known to direct the hydrogenation by the Crabtree catalyst is highly regioselective.
Specification
ITEMS | SPECIFICATION |
| Appearance | Yellow to orange solid |
MDL No | MFCD00075097 |
Melting Point | 175 °C |
Sensitivity | Air Sensitive,Moisture Sensitive |
Solubility | Slightly soluble in acetone, dichloromethane, ethanol and diethyl ether. Insoluble in water |
Storage condition | Inert atmosphere, Room Temperature |
Reference
Seidel, D.; Pleiss, U. Labelling of the guanylate cyclase activator cinaciguat (BAY 58-2667) with carbon-14, tritium and stable isotopes. J. Labelled Compd. Radiopharm. 2010, 53 (3), 130-139.
Chappelle, M. R.; Hawes, C. R. The use of metal-catalysed hydrogen isotope exchange in the contract supply of tritiated compounds. J. Labelled Compd. Radiopharm. 2010, 53 (11-12), 745-751.
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