CAS:14264-16-5 | Bis(triphenylphosphine)nickel(II) Dichloride
Molecular Formula:C36H30Cl2NiP2
Molecular Weight:654.17
EINECS:238-154-8
Purity:98%
Package:5g/10g/25g/50g/bulk package
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Product Introduction
Name | Bis(triphenylphosphine)nickel(II) dichloride |
Synonyms | Dichlorobis(triphenylphosphine)nickel(II) |
CAS | 14264-16-5 |
MDL No | MFCD00009592 |
Boiling Point | 360ºCat 760 mmHg |
Melting Point | 250 °C (dec.)(lit.) |
Flash Point | 181.7ºC |
PSA | 27.18 |
LogP | 4.58 |
Appearance | Dark green to Dark blue to Black powder to crystal |
Sensitivity | Air &Hygroscopic Sensitive |
Solubility | Very slightly in ethanol,ether,insoluble in water |
Storage condition | Inert atmosphere,Room Temperature |
InChI | InChI=1/2C18H15P.2ClH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2 |
InChIKey | InChIKey=ZBRJXVVKPBZPAN-UHFFFAOYSA-L |
Application:
Dichlorobis(triphenylphosphine)nickel(II)(CAS:14264-16-5) is used as a catalyst for cross-coupling of Grignard reagents, hydrosilylations, hydrogenation and polymerization.
References:
Daniel R. Palo.; Can Erkey. Solubility of Dichlorobis(triphenylphosphine)nickel(II) in Supercritical Carbon Dioxide. J. Chem. Eng. 1998, 43 (1), 47-48.
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