CAS:920-39-8 | Isopropylmagnesium Bromide

Name:Isopropylmagnesium Bromide

Synonyms:magnesium,propane,bromide;I-PROPYL MAGNESIUM BROMIDE;MAGNESIUM,BROMO(1-METHYLETHYL)-;ISPROPYLMAGNESIUM BROMIDE;ISOPROPYLMAGNESIUMBROMIDE;ISO-PROPYLMAGNESIUM BROMIDE;I-PROPYLMAGNESIUM BROMIDE;ISOPROPYLMAGNESIUM BROMIDE;

CAS:920-39-8

Purity:99%

Molecular Formula:C₃H₇BrMg

Molecular Weight:147.30

Melting Point:114-116ºC

Boiling Point:N/A

Flash Point:-17ºC

PSA:0.00

LogP:2.21

Appearance:Clear dark brown or dark gray solution

Stability:Moisture Sensitive,Air Sensitive. 

Solubility:Miscible with tetrahydorfuran and diethyl ether. Immiscible with hydrocarbons.

Storage condition:Store under Argon. Ambient temperatures.

Application:Isopropylmagnesium bromide(CAS:920-39-8) is a Grignard reagent used in organic synthesis, especially for the introduction of iso-propyl group to carbonyl compounds. It is also used as a strong base in aprotic solvent.

Reference: 

Du, B. X.; Quan, Z. J.; Da, Y. X.; Zhang, Z.; Wang, X. C. Chemo-Controlled Cross-Coupling of Di(hetero)aryl Disulfides with Grignard Reagents: C-C vs. C-S Bond Formation. Adv. Synth. Catal. 2015, 357 (6), 1270-1276.

Roy, A.; Bhat, B. A.; Lepore, S. D. Organo-Manganese η2-Auxiliary Directed Reactions: A Diastereoselective Approach to 2, 3-Allenols. Org. Lett. 2015, 17 (4), 900-903.

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